Sprinkle pork chops with pepper and salt. Place flour in a large resealable plastic bag; add the pork chops, one at a time, and shake to coat.
In a large nonstick skillet coated with cooking spray, brown chops on both sides. Transfer to an ungreased 11-in. x 7-in. baking dish. Top with tomatoes, mushrooms, onions and olives. Sprinkle with garlic, basil and oregano.
Cover and bake at 350° for 35-40 minutes or until a thermometer reads 160°. Yield: 4 servings.